2012年6月17日星期日

What's We Know About Divinylbenzene




Product name:Divinylbenzene
CAS:1321-74-0
Molecular Formula:C10H10
Formula Weight:130.19g/mol
Description of Divinylbenzene:
Divinylbenzene (DVB) consists of a benzene ring bonded to two vinyl groups. It is related to styrene (vinylbenzene) by the addition of a second vinyl group. Divinylbenzene, as it is usually encountered, is a 2:1 mixture of m- and p-divinylbenzene, containing also the corresponding ethylvinylbenzene isomers. It is manufactured by the thermal dehydrogenation of isomeric diethylbenzenes. Under synthesis conditions, o-divinylbenzene converts to naphthalene and thus is not a component of the usual mixtures of DVB.
Reactivity Profile:
Divinylbenzene may react vigorously with strong oxidizing agents. Can react exothermically with reducing agents (such as alkali metals and hydrides) to release gaseous hydrogen. May react exothermically with both acids and bases. May in the presence of various catalysts (such as acids) or initiators undergo exothermic polymerization. Inhibited by presence of an additive. When uninhibited violent polymerization may occur . Substitution at the benzene nucleus occurs by halogenation (acid catalyst), nitration, sulfonation, and the Friedel-Crafts reaction.
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